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•Correspondence with Jonn Mackay (1800-1801), G.A. Walker Arnott (1828), P. Neill (1828), J. McNab (1834), R. Graham (1826), and also referenced to correspondence with G. Don (1802-1812) and W.M. McNab (1818 and 1823).

•Notebook containing an article for ‘Theosophist’ Aug – Nov 1917, titled “Francis Bacon and the Cipher Story”

•Letter to P. Neill Fraser (7 Nov 1904)

3 small notebooks numbered 1-3, and a letter
1:"Herb. Irvine 1"
Collecting Book 1 - Nos 1-862 1949-1965; incl. St Andrews, Bangor, Anglesey, Isle of Man, Eden Estuary, Aberystwyth, Merioneth, Pembrokeshire, Capri (Italy), Brittany (France), Galway, Mayo, Manitoba (Canada), Cape Cod (Massachusetts), Orkney and Voe (Shetland)
2:"Herb.Irvine 2"
Collecting Book 2 - Nos 863-1847 1964-1968; incl. Anglesey, Pembrokeshire, Portsmouth, Dover-Folkestone, Cramond Island, Dunbar, North Berwick, Scilly, Devon and Paignton
3:"Herb.Irvine 3"
Collecting Book 3 - Nos 1848-1940 (Misc Order) 1963-1969 inc. Firth of Forth?
4:letter from Linda M. Irvine which accompanied herbarium consignment, filed in RBGE Archives Accessions folder under RBGEEA2015/23

1 sketchbook showing scenes of life in Burma (plus one sketch of Loch Eck)

2 limited edition hand coloured multi block wood engravings showing the plantsman Reginald Farrer created in 2015 by artist Abigail Rorer of the Lone Oak Press.

drawings and photographs used to illustrate Mann's thesis and drawings on permatrace used in other publications.

Added in 2020 (RBGEA2020/007):

3 sets of postcards depicting algae or diatoms as follows:

• 3 envelopes of Algal picture postcards from M. Adei; Scanning electron micrographs of diatoms (1994); Marine algae in coral reef (1993); and Algal vegetation in cold current area (1993)
• pack of 12 poscards from the British Bryological Society (1994)
• pack of Stereographs of the Diatom World, The Educational Association of Algae (2002)

1 ledger, 1 boxfile and 1 lever arch ring binder of material relating to the running of the Edinburgh Microscopical Society

5 boxes of slides, totalling around 400 slides, and an envelope "Botanic Garden Notes" (now in Box 1) of news clippings relating to the opening of the Glasshouses.

1 marble bust, sculpted by William Brodie R.S.A. in 1860.